So far I see nothing wrong with the INI file. Well, expect for the "garbage" at the end which should be removed of course.
ConnectMeNow will ignore these "extra" servers, but for all purposes they should have been removed - which shouldn't be too hard to do.
The Mac Address looks good too, so I'm unsure what the "problem" might be.
as far as I understand from you:
1) When clicking "Auto Find Mac", WOL works, one time only.
2) When entering manual, or after restart, WOL does NOT work.
So to me that suggests something goes wrong with the Mac Address, or everything I use for WOL.
Your Mac Address (0030) looks valid, and you already confirmed that manual an auto have the same Mac Address.
I'll try to run a test here (I'm staying at a hotel in Houston, so not much WOL going on here haha) and see if something weird happens.
Interestingly enough though, miniWOL, as used by my brother-in-law, consistently keeps working just fine.
Debugging might reveal something.