I have not had issue with this ... after a certain idle time, my LEDs dim (I think I did that through the Boblight plugin).
An option to consider, if it's just a matter of switching OFF when you shutdown your HTPC;
Use a relay on the Arduino to switch the power supply for the LEDs ON when the Arduino powers ON.
Once power drops, the relay will release and the power of the LEDs will be switched OFF as well.
Just an idea ... (this Instructable might be helpful!)
I suspect that you can do it with a script as well and assign it a remote control button (although I prefer things to automatically go off).
I did find this topic in the OpenElec Forum. and this one.
There is also something mentioned in the official XBMC Boblight Addon thread.
From that thread:
You can access the settings during video playback. For this just put the file script.xbmc.boblight.keymap.xml found HERE into your "userdata/keymaps" folder.
script.xbmc.boblight.keymap.xml:
<keymap>
<fullscreenvideo>
<keyboard>
<b>Addon.OpenSettings(script.xbmc.boblight)</b> <!-- shortcut key b to boblight settings -->
<B>Addon.OpenSettings(script.xbmc.boblight)</B> <!-- shortcut key B to boblight settings -->
</keyboard>
</fullscreenvideo>
</keymap>
I did also see this script in kodiers.net (German).
Just some thoughts ... I'll try to look into this some more ...